1 grams Methane is equal to 0.062334579609362 . Measurements made at a particular site and height represent the conditions of the underlying surface upwind of the sensor. Moreover, during the last decade, a process-based model (CALMIM, California Landfill Methane Inventory Model) has been developed and field validated to provide a predictive framework for site-specific climate and cover-specific gaseous transport and oxidation processes over a typical annual cycle (Spokas et al., 2011, 2015). In addition to various spatial scales, both top-down and bottom-up approaches have varying temporal scales. (2016) of about 15,000 measurements from 18 studies (including many cited in Table 3.3) found that methane emissions from natural gas systems follow an extreme distribution, resulting in a small fraction of observed emissions accounting for a vast majority of the emissions from the population sampled. Both forward and inverse modeling approaches are powerful analysis tools that can increase understanding of the global and regional budget of methane. concentration and the driving force for diffusive methane emissions to the atmosphere (Spokas et al., 2011). The EPA carries out a verification process on all data received to ensure it's "accurate, complete, and consistent." Verified data is made publicly accessible online, opening companies to public scrutiny and comparisons. This methane drainage reduces the gas content of the coal and decreases the risk of gas outbursts by decreasing the pressure in the rock formations (Karacan et al., 2011; Noack, 1998). As shown in Chapter 2, however, bottom-up inventories of emissions may not account for all sources, and, as outlined in this chapter, the methods may have uncertain or inaccurate activity data and emission factors. Methane emissions have a clear diurnal pattern, related to feed intake (usually lower at night) and therefore, for accurate daily emission estimates, animal visits have to be spread out over a 24-hour feeding cycle. British thermal units (Btu) - U.S. Energy Information Administration (EIA) Regional emissions are then estimated by subtracting the flux out of the region from the flux into the region. You can view more details on each measurement unit: molecular weight of Methane or grams The molecular formula for Methane is CH4 . Hellwing et al. Emission rates are estimated using a mass balance approach; the concentration differences between the upwind and downwind portions of the flight paths are multiplied by the ventilation rate for the volume enclosed by the flight paths to arrive at the emission estimate (e.g., Conley et al., 2017; Gvakharia et al., 2017). (2014) to the conclusion that variability in tropical emissions is larger if SCIAMACHY retrievals are used in addition to surface observations and that the variability is more robust if bias correction parameters are not estimated along with emissions in the inversion. No systematic differences between global nested-grid and Lagrangian inversions were highlighted; however, the Lagrangian inversions used background methane from the global inversions, thereby eliminating a major source of difference between the two approaches. This report will inform future research agendas of various U.S. agencies, including NOAA, the EPA, the DOE, NASA, the U.S. Department of Agriculture (USDA), and the National Science Foundation (NSF). The seasonal cycle of methane is on the order of tens of parts per billion, while decadal trends have ranged from <1 to >10 ppb yr1.9 The ability to accurately quantify trends and spatial gradients that allow continental or regional emissions to be inferred places strong demands on the precision and accuracy of network observations. The company has closely collaborated with numerous government and academic organizations. GWP100 assumed that all greenhouse gases were stagnant in the atmosphere, meaning they remained there for centuries. Emissions from ruminants and manure were found to be as much as a factor of 2 higher than estimated by the EPA and EDGARv4. Finding and mitigating methane leaks is critical for the US energy infrastructure to remain competitive and improve its carbon footprint. Schwietzke et al. This indicator describes how the levels of major greenhouse gases in the atmosphere have changed over time. Multiple field campaigns during the last two decades have greatly improved understanding of landfill methane emission processes at U.S. sites. Rental Products A number of sampling technologies exist for measuring methane in a variety of applications, from source/stack testing to leak detection to CEMS. (2017) improved the mass balance methods by explicitly accounting for nonuniform upwind methane mole fractions in the planetary boundary layer in the study area. Aircraft-based measurements of methane, ethane, carbon dioxide, carbon monoxide, and other compounds downwind of production region (but not upwind). (2015), among others, discussed the difficulty of disentangling transport errors from errors in specifying the locations of the emission sources. 3.5% of controllers accounted for 73% of controller emissions. The advantage of using a regional atmospheric model is that transport can be simulated at higher resolution and is likely to be more accurate than with a coarser global model. The measured emissions will include both enteric (for barns) and manure. Measurement of path-integrated methane along boundaries of a source area (i.e., ppm methane-m) along with wind characteristics to estimate an emission rate. Bottom-up approaches are also described, and recent measurement techniques used for specific source categories are reviewed. on roughly the same latitude as California. A common element in many of the recent methane emission studies on natural gas is the presence of high-emitting sources, that is, a small number of sites or equipment that contribute a disproportionately high fraction of the cumulative total emissions recorded (Box 2.2). But, under the hood of this fairly straightforward observation is a veritable thicket, in the form of every engineers best friend: units. Global warming potential (GWP) is a measure of how much infrared thermal radiation a greenhouse gas added to the atmosphere would absorb over a given time frame, as a multiple of the radiation that would be absorbed by the same mass of added carbon dioxide (CO 2).GWP is 1 for CO 2.For other gases it depends on the how strongly the gas absorbs infrared thermal radiation, how quickly the gas . Atmospheric methane by infrared spectrometry at precise infrared wavelengths for pristine sites remote from population centers. The GHGRP requires reporting of greenhouse gas (GHG) data and other relevant information from large GHG emission sources, fuel and industrial gas suppliers, and CO 2 injection sites in the United States. The flux gradient technique determines the vertical flux of a gas at a given height as a product of the gass turbulent diffusivity and the concentration gradient at that height (Laubach and Kelliher, 2004). While carbon dioxide is by far the dominant cause of the rise in global average temperatures, methane also plays a significant role because it absorbs more energy per unit mass than carbon dioxide does, giving it a disproportionately large effect on global radiative forcing. Differences between forward simula-. Some measurements of high emissions may be due to the size of the facility. Scientists are also able to compare by converting the different GWP values of each potent greenhouse gas into CO2-equivalents, much like converting between different units (ex. For static. Table 3.4 summarizes recent aircraft measurements that have been made primarily in petroleum, TABLE 3.4 Sample of Regional Methane Emission Studies Conducted Using Aircraft Plus Complementary Data. Other emission inventory changes have been due largely to changes in activity counts. Elsewhere in the world, where the metric system is used, the amounts are usually reported in cubic meters (m 3).A convenient conversion factor is 35.3 ft 3 /m 3. Observed for unloadings, pneumatic controllers. In addition, in the petroleum and gas category, activity and emission factor data collection activities are linked. As discussed in Chapter 2, the EPA produced a methodology for abandoned underground mines in the United States (EPA, 2004), and annually reports methane emissions. In underground coal mining, activity data such as numbers of mines and quantities of coal produced are well known and emission estimates rely on stack-based sampling of. This can in turn improve inventory development on larger scales by identifying the drivers of underlying discrepancies per source category. Similar to the SF6 technique, GF cannot measure methane excreted through the rectum. At smaller spatial scales, measurements from single processes, individual sources, or components within a facility are extrapolated to larger scales (regional, national, global). DOE estimates that the adopted standards will result in cumulative emission reductions (over the same period as for energy savings) of 91.69 million metric tons (``Mt'') \7\ of carbon dioxide (``CO 2 ''), 35.12 thousand tons of sulfur dioxide (``SO 2 ''), 148.74 thousand tons of nitrogen oxides (``NO X ''), 690.10 thousand tons of methane (``CH . Top-down measurements confirmed the daily variability in emissions, and overall, the study confirmed that knowledge of both local facilities and daily operational schedules are important in comparing top-down and bottom-up emission estimates. For enclosed barns that are mechanically ventilated, emission rates can be determined by mass balance methods. Common simple methods of measuring flow rates are bagging, in the case of leaks, or in the case of controlled flow, by using a flow metering device. Gaussian-based plume dispersion modeling showed that methane emission rates can range over an order of magnitude for a single mine (EPA, 2005). Eructated and expired gas is continuously sampled around the nostrils of the animal into an evacuated container and the gas is analyzed for SF6 and methane. Imagine you have two bathtubs. Convert grams Methane to moles - Conversion of Measurement Units Even so, methane that has broken down into CO2 is still carbon in the atmosphere. With the collective threat of climate disasters like flooding, drought, and more spreading around the globe, scientists are searching for ways to help reduce human-based impacts on the climate. For example, a too-stable planetary boundary layer could systematically lead to underestimated emissions. Units and calculators explained - U.S. Energy Information Top-down estimates have also been produced for specific regions of the United States. Methane must fall to slow global heatingbut only 13% of emissions are The Paris Climate Accord set goals to limit global warming to 1.5 degrees Celsius. Downwind sampling of sites, with onsite measurements and emission estimates. yr1). Empirical methods typically require only a few input parameters (e.g., coal production, gas content, and methane emission rate), but with the large number of parameters that influence emissions, the accuracy of the results is not always satisfactory (Karacan et al., 2011). Not as accurate as in situ data, emissions not cleanly resolved. They can also be employed over longer time periods that capture the temporal variability of emissions, providing better long-term emission estimates. 12 See http://www.globalcarbonproject.org/methanebudget/index.htm. Static chambers quantify emissions by multiplying the change in methane concentration over short monitoring periods by the chamber volume/area ratio. Consequently, gassy underground U.S. mines have high-resolution methane emission data collected underground. For many other sites, however, a high percentage of total site emissions can be attributed to intermediate cover areas, which typically cover large areas and have thinner cover soils than final covers (see Spokas et al., 2015, addressing California emissions). Methane in coal can be generated thermogenically, as part of the coalification process,6 or biogenically owing to activity of microbes. They may provide guidance on whether policy aimed at mitigating methane emissions is effective, and they may alert scientists of increased emissions from Arctic wetlands and permafrost. If the vehicle drives along a path that is perpendicular to the wind direction, the horizontal extent of the plume can be determined. While horizontal boreholes are often used to capture methane, surface boreholes are used to control seam gas and are typically vented into the atmosphere. Another indirect method proposed by Garnsworthy et al. A typical approach is to fly concentric closed flight paths at multiple altitudes around a source while continuously measuring methane concentrations, wind speed, and wind. Very high combustion efficiencies (>99.5%) for a single well completion flare; bottom-up inventories generally assume 98% efficiency. However, only one of these bathtubs has a drain. Flow meters can measure flow rates either by mass or by volume. (2013) found that emissions from fossil fuel production could be almost five times larger than estimated by EDGAR. While chamber systems can be utilized to measure emissions from ruminants and nonruminants, there are a variety of other techniques available to measure enteric methane emissions from ruminant animals. Appropriate topographic and meteorological conditions are necessary for technique to work properly. The main principles of dynamic respiration chambers are to measure incoming and exhaust airflows, concentration of gases of interest in that air, and initial and final gas concentrations in the chamber. Efforts to develop direct methane measurements or mine-specific assessments in surface coal mines of the United States and elsewhere have also been attempted. methane emissions in the region (Zavala-Araiza et al., 2015) wherein estimates from both approaches converged, but this convergence was possible because of (1) a spatially resolved inventory wherein the national activity data for bottom-up estimates were supplemented by local counts of facilities and (2) enhanced sampling strategy and application of a statistical model to account for and characterize high-emitting facilities. (2011) evaluated and compared a suite of atmospheric transport models for 1990-2007 using observations of methane, radon, SF6, and methyl chloroform at background sites and satellite retrievals of methane in the upper troposphere and stratosphere. (1997) used a full global atmospheric transport model to estimate global methane emissions and concluded that their estimated emissions reproduced large-scale features such as the interhemispheric methane gradient reasonably well, but not grid-scale emission variability. perimeter facility line measurements, inverse dispersion modeling, and external tracer methods to derive atmospheric methane transport rates over square kilometer scales. Facility-level emissions will include emissions originating from both enteric emissions and manure management, while manure management emissions aim to target those emissions originating from manure in housing as well as manure handling and storage areas.
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